The hot-dip galvanizing (HDG)
process consists of three basic steps:
- Surface Preparation
- Galvanizing
- Inpection
Surface preparation is the most
important step in the application of any coating. In most instances
where a coating fails before the end of its expected service life, it is
because of incorrect or inadequate surface preparation. The galvanizing
process has its own built-in means of quality control because zinc will not
react with an unclean steel surface. Any failures or inadequacies in surface
preparation will be immediately apparent when the steel is withdrawn from the
zinc bath because the unclean areas will remain uncoated, and immediate
corrective action can be taken.
Surface preparation for galvanizing
consists of three steps:
Degreasing/Caustic
Cleaning
A hot alkali solution, mild acidic
bath, or biological cleaning bath removes organic contaminants such as dirt,
paint markings, grease, and oil from the metal surface. Epoxies, vinyls,
asphalt, or welding slag, which cannot be removed by degreasing, must be
removed before galvanizing by grit-blasting, sand-blasting, or other
mechanical means.
Pickling
A dilute solution of heated sulfuric
acid or ambient hydrochloric acid removes mill scale and iron oxides (rust)
from the steel surface. As an alternative to or in conjunction with pickling,
this step can also be accomplished using abrasive cleaning or air blasting
sand, metallic shot, or grit onto the steel.
Fluxing
The final surface preparation step
in the galvanizing process, a zinc ammonium chloride solution, serves two
purposes. It removes any remaining oxides and deposits a protective layer on
the steel to prevent any further oxides from forming on the surface prior to
immersion in the molten zinc.
Galvanizing
During the true galvanizing step of
the process, the material is completely immersed in a bath of molten
zinc. The bath chemistry is specified by ASTM B6,
and requires at least 98% pure zinc maintained at 815-850 F (435-455 C).
While immersed in the kettle, the
zinc reacts with the iron in the steel to forma series of metallurgically
bonded zinc-iron intermetallic alloy layers, commonly topped by a layer of
impact-resistant pure zinc.
Once the fabricated items’ coating
growth is complete, it is withdrawn slowly from the galvanizing bath, and the
excess zinc is removed by draining, vibrating, and/or centrifuging.
The metallurgical reaction will
continue after the materials are withdrawn from the bath, as long as it remains
near bath temperature. Galvanized articles are cooled either by immersion in a
passivation solution or water or by being left in open air.
Inspection
The inspection of hot-dip galvanized steel is simple and quick. The two properties of the hot-dip
galvanized coating most closely scrutinized are coating thickness and appearance/surface condition. A variety of simple physical tests can be performed to
determine thickness, uniformity, adherence, and appearance.
Products are galvanized according to
long established, accepted, and approved standards of ASTM, the International
Standards Organization (ISO), the Canadian Standards Association (CSA), and the
American Association of State Highway and Transportation Officials
(AASHTO). These standards cover everything from the minimum coating
thicknesses required for various categories of galvanized items to the
composition of the zinc metal used in the process.
http://www.galvanizeit.org/hot-dip-galvanizing/what-is-hot-dip-galvanizing-hdg/hdg-process
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